fig3
Figure 3. Electrochemical and thermal characterization of layered MnO2 electrodes. (A) Ex situ TGA curves of pristine, charged, and discharged electrodes under argon atmosphere. (B) Typical galvanostatic charge-discharge (GCD) profiles of the layered MnO2 electrode. (C) Rate performance of the layered MnO2 electrode at various current densities. (D) Log(i) vs. log(v) plot for the layered MnO2 electrode, illustrating the b-value analysis of charge-storage kinetics. (E) Non-diffusion-controlled (capacitive) current contribution at a scan rate of 5 mV s-1. (F) Histogram showing the capacitive contribution at scan rates from 1 to 5 mV s-1. (G) Calculated migration pathway and energy barrier of SO42- within the modeled MnO2 interlayer environment.






