fig4
Figure 4. (A) Schematic illustration for the casting process of a key with a mold (A1) and nanocasting using ordered mesoporous materials as the hard template (A2). Figure 4A is quoted with permission from Deng et al.[70]; (B) TEM images of mesoporous WO3 synthesized using KIT-6 as the template (B1, B2); HRTEM image of the ring-like structure, with the inset showing the corresponding FFT pattern (B3); uncoupled framework model (B4). Figure 4B is quoted with permission from Rossinyol et al.[79]; (C) Schematic illustration of the EIAA strategy. Figure 4C is quoted with permission from Jianget al.[24]; (D) Schematic illustration of the one-pot direct synthesis of PB-b-PDMAEMA/H3[PMo12O40] nanocomposite films. Figure 4D is quoted with permission from Lunkenbein et al.[85]; (E) Schematic illustration of the citrate ligand-assisted EISA method for synthesizing crystalline mZnO. Figure 4E is quoted with permission from Zhou et al.[25]; (F) Schematic illustration of the synthesis routes for mesoporous metal oxides via metal carbonate intermediates. Figure 4F is quoted with permission from Eckhardt et al.[86]; (G) TEM images of multicomponent mesoporous metal oxides prepared with acetate chelation assistance. Figure 4G is quoted with permission from Fan et al.[87]. THF: Tetrahydrofuran; TEM: transmission electron microscopy; HRTEM: high-resolution transmission electron microscopy; FFT: fast Fourier transform; EIAA: evaporation-induced aggregate assembly; PDMAEMA: poly(2-(dimethylamino)ethyl methacrylate); H3[PMo12O40]: phosphomolybdic acid; mZnO: mesoporous zinc oxide.



